三氯化丁基锡

Description

Butyltin trichloride · CAS 1118-46-3 · C4H9Cl3Sn. UNII 9R2DZM42GM. Boiling Point: 102 °C @ 12 mm Hg; Melting Point: -63 °C; Flash Point: 81 °C (closed cup).

Identification

CAS Registry Number	1118-46-3
PubChem CID	14236
Molecular formula	C4H9Cl3Sn
IUPAC name	butyl(trichloro)stannane
UNII (FDA)	9R2DZM42GM

Computed Descriptors

Molecular Weight	282.2
Hydrogen Bond Donor Count	0
Hydrogen Bond Acceptor Count	0
Rotatable Bond Count	2
Exact Mass	281.879186
Monoisotopic Mass	281.879186
Topological Polar Surface Area	0
Heavy Atom Count	8
Formal Charge	0
Complexity	58.8

Physical & Chemical Properties

Boiling Point	102 °C @ 12 mm Hg
Melting Point	-63 °C
Flash Point	81 °C (closed cup)
Density	1.71 at 25 °C/4 °C
LogP	log Kow= 0.41

Physical description & handling notes

• Liquid; Dry Powder
• Colorless liquid; [HSDB] Yellow to red clear liquid; [MSDSonline]
• Colorless liquid
• Sol in organic solvents; sparingly sol in water with partial hydrolysis
• FUMES IN CONTACT WITH AIR
• When heated to decomposition it emits toxic fumes of Cl- /chlorides/.

Regulatory Status

GHS notification summary	5% (6 / 120)

GHS Hazard Classification

GHS notification summary	5% (6 / 120)
Reported hazard statements	H302 (40%), H314 (55.8%), H315 (39.2%), H318 (20%), H319 (39.2%), H332 (33.3%), H335 (50%), H341 (39.2%)

Documented Uses

• A degradation product of dibutyltin and tributyltin (antifouling agents in marine paints); Used as an intermediate for other mono-n-butyltin compounds, a PVC stabilizer, and a hot-end coating of glass bottles; [HSDB]
• Glass Manufacturing [Category: Industry]
• Hot-end coating of glass to improve abrasion resistance and bursting strength of glass bottles.
• Although generally less effective than dialkyl tin compounds as PVC stabilizers, monoalkyltin compounds when added to dialkyltin compounds in amounts of 5-20 wt% exert a synergistic effect on stabilizer effectiveness, preventing early yellowing.
• REDISTRIBUTION REACTION OF TETRA-N-BUTYLTIN & STANNIC CHLORIDE IN AN APPROX 1:3 RATIO TO FORM A MIXTURE OF CHLOROBUTYLTINS, FOLLOWED BY SEPN; OXIDATIVE ADDITION OF N-BUTYL CHLORIDE TO STANNOUS CHLORIDE IN THE PRESENCE OF TRI-N-BUTYLANTIMONY CATALYST.
• The oxidative addition of aliphatic organic halides to stannous chloride has long been of interest for the preparation of monoorganotin trihalides. Fair to good yields are obtained for the reaction with quaternary ammonium or phosphonium catalysts. Trialkylantimony compounds at 100-160 °C are also used as catalyst.

Synonyms

Butyltin trichloride; 1118-46-3; Butyltrichlorostannane; Stannane, butyltrichloro-; N-Butyltin trichloride; Butyltrichlorotin; MONOBUTYLTIN TRICHLORIDE; Trichlorobutyltin; Trichlorobutylstannane; Stannane, trichlorobutyl-; Monotributyltin trichloride; Mono-n-butyltin trichloride; Chlorid n-butylcinicity; Butylstannium trichloride; DTXSID0029210; Tin, n-butyl-, trichloride

Frequently Asked Questions

What are the CAS number and molecular formula of Butyltin trichloride?

CAS 1118-46-3; molecular formula C4H9Cl3Sn; molecular weight — g/mol.

What other names is Butyltin trichloride known by?

Butyltin trichloride, 1118-46-3, Butyltrichlorostannane, Stannane, butyltrichloro-, N-Butyltin trichloride, Butyltrichlorotin.

Is Butyltin trichloride classified as hazardous?

5% of GHS notifications report no hazard classification (6 of 120).

What are the key physical properties of Butyltin trichloride?

Boiling Point: 102 °C @ 12 mm Hg; Melting Point: -63 °C; Flash Point: 81 °C (closed cup); Density: 1.71 at 25 °C/4 °C.

Facts on this page are taken from PubChem (US National Library of Medicine) and Wikidata. Grade-specific data — assay, moisture, particle size, packaging, shelf life — is issued per batch on the COA and is not published here.