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Cryolite

CAS 15096-52-3AlF6.3NaMW 209.941265

Cryolite (CAS 15096-52-3) — formula AlF6.3Na, molecular weight 209.941265; category organic chemicals.

Specifications

CAS Number15096-52-3
Molecular FormulaAlF6.3Na
Molecular Weight209.941265
Melting Point1832 °F (NIOSH, 2024)
ApplicationsUses: Used as an electrolyte in the production of aluminum by electrolytic reduction, [ACGIH], Aluminum Producing [Category: Industry], For Cryolite (USEPA, OPP Pesticide Code: 075101) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., Primarily a stomach poison. ... For use against Lepidoptera & Coleoptera on certain vegetables & fruit crops ... ., Principally an electrolyte in production and refining of aluminum, flux in production of various metals and alloys, flux and opacifier in manufacture of glass and enamels, coating for welding rods, filler for resin, rubber, ceramic-bonded grinding wheels, Electrolyte in the reduction of alumina to aluminum, ceramics, insecticide, binder for abrasives, electric insulation, explosives & polishes., For more Uses (Complete) data for ALUMINUM SODIUM FLUORIDE (9 total), please visit the HSDB record page., Use Classification: INSECTICIDES, Industry Uses: Catalyst, Not Known or Reasonably Ascertainable, Filler, Flux agent, Abrasives, Consumer Uses: Abrasives, Methods of Manufacturing: Reaction of hydrofluoric acid, hydrated alumina, and sodium carbonate., It is commonly produced by mixing sodium aluminate soln with liquid or gaseous hydrogen fluoride., ... Synthetically from aluminum fluoride, ammonium fluoride and salt., Synthetic cryolite is usually made from sodium aluminate, sodium bicarbonate, and sodium fluoride., Cryolite may be obtained by (a) mining natural mineral cryolite or (b) synthesis by the reaction of aluminum oxide, sodium chloride and hydrogen fluoride., Formulations, Preparations: Kryocide, insecticide produced by Pennwalt, 96% sodium fluoaluminate, Aqueous suspension, bait, dust and wettable powder., ... Generally and 0.2% suspension, as insecticide, Consumption Patterns: About 75% in the production and refining of aluminum, 25% in all other applications (1965), Seven thousand metric tons were applied in the United States in 1944., U.S. Production: 2023: 10, 000, 000 - <50, 000 lb, 2022: 10, 000 - <25, 2021: 10, 2020: 8, 500, 000 - <10, (1972) AT LEAST 8.8X10+10 G, U.S. Imports: (1972) 2.33X10+10 G, (1973) 3.48X10+10 G, General Manufacturing Information: All Other Basic Inorganic Chemical Manufacturing, Primary Metal Manufacturing, Other (requires additional information), Machinery Manufacturing, Miscellaneous Manufacturing, Aluminum sodium fluoride: INACTIVE, Cryolite (Na3(AlF6)): ACTIVE, Cryolite is, incompatible with alkaline pesticides such as lime sulfur, bordeaux mixture., With lime, cryolite undergoes ..., a chemical, reaction, that, ... Results in plant injury., Cryolite ... is the primary constituent of the Hall-Heroult cell electrolyte., ... Developed as a safer stomach poison insecticide than the arsenicals, especially because of concern about persistent lead arsenate residues on edible produce such as apples., ... Widely exploited since the early days of commercial aluminum production, but now practically exhausted and abandoned in favor of synthetic cryolite.
CategoryOrganic Chemicals

Where it is used

Documented applications: Uses: Used as an electrolyte in the production of aluminum by electrolytic reduction, [ACGIH], Aluminum Producing [Category: Industry], For Cryolite (USEPA, OPP Pesticide Code: 075101) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., Primarily a stomach poison. ... For use against Lepidoptera & Coleoptera on certain vegetables & fruit crops ... ., Principally an electrolyte in production and refining of aluminum, flux in production of various metals and alloys, flux and opacifier in manufacture of glass and enamels, coating for welding rods, filler for resin, rubber, ceramic-bonded grinding wheels, Electrolyte in the reduction of alumina to aluminum, ceramics, insecticide, binder for abrasives, electric insulation, explosives & polishes., For more Uses (Complete) data for ALUMINUM SODIUM FLUORIDE (9 total), please visit the HSDB record page., Use Classification: INSECTICIDES, Industry Uses: Catalyst, Not Known or Reasonably Ascertainable, Filler, Flux agent, Abrasives, Consumer Uses: Abrasives, Methods of Manufacturing: Reaction of hydrofluoric acid, hydrated alumina, and sodium carbonate., It is commonly produced by mixing sodium aluminate soln with liquid or gaseous hydrogen fluoride., ... Synthetically from aluminum fluoride, ammonium fluoride and salt., Synthetic cryolite is usually made from sodium aluminate, sodium bicarbonate, and sodium fluoride., Cryolite may be obtained by (a) mining natural mineral cryolite or (b) synthesis by the reaction of aluminum oxide, sodium chloride and hydrogen fluoride., Formulations, Preparations: Kryocide, insecticide produced by Pennwalt, 96% sodium fluoaluminate, Aqueous suspension, bait, dust and wettable powder., ... Generally and 0.2% suspension, as insecticide, Consumption Patterns: About 75% in the production and refining of aluminum, 25% in all other applications (1965), Seven thousand metric tons were applied in the United States in 1944., U.S. Production: 2023: 10, 000, 000 - <50, 000 lb, 2022: 10, 000 - <25, 2021: 10, 2020: 8, 500, 000 - <10, (1972) AT LEAST 8.8X10+10 G, U.S. Imports: (1972) 2.33X10+10 G, (1973) 3.48X10+10 G, General Manufacturing Information: All Other Basic Inorganic Chemical Manufacturing, Primary Metal Manufacturing, Other (requires additional information), Machinery Manufacturing, Miscellaneous Manufacturing, Aluminum sodium fluoride: INACTIVE, Cryolite (Na3(AlF6)): ACTIVE, Cryolite is, incompatible with alkaline pesticides such as lime sulfur, bordeaux mixture., With lime, cryolite undergoes ..., a chemical, reaction, that, ... Results in plant injury., Cryolite ... is the primary constituent of the Hall-Heroult cell electrolyte., ... Developed as a safer stomach poison insecticide than the arsenicals, especially because of concern about persistent lead arsenate residues on edible produce such as apples., ... Widely exploited since the early days of commercial aluminum production, but now practically exhausted and abandoned in favor of synthetic cryolite..

Purchase Profile

What this product is

Cryolite is a carbon-based organic compound with CAS registry number 15096-52-3 and molecular formula AlF6.3Na (molecular weight 209.941265), belonging to the organic chemicals segment of chemical raw materials.

Identification

CAS number: 15096-52-3

Its molecular formula AlF6.3Na comprises 1 Al, 6 F, 1 Na atoms.

Also known as: Cryolite · Trisodium hexafluoroaluminate

Category: organic chemicals

Frequently Asked Questions

What is the CAS number of Cryolite?

The CAS registry number of Cryolite is 15096-52-3.

What is the molecular formula and molecular weight of Cryolite?

Molecular formula AlF6.3Na, molecular weight 209.941265.

What other names is Cryolite known by?

It is also registered under: Cryolite, Trisodium hexafluoroaluminate.

What are the documented applications of Cryolite?

Recorded applications: Uses: Used as an electrolyte in the production of aluminum by electrolytic reduction, [ACGIH], Aluminum Producing [Category: Industry], For Cryolite (USEPA, OPP Pesticide Code: 075101) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., Primarily a stomach poison. ... For use against Lepidoptera & Coleoptera on certain vegetables & fruit crops ... ., Principally an electrolyte in production and refining of aluminum, flux in production of various metals and alloys, flux and opacifier in manufacture of glass and enamels, coating for welding rods, filler for resin, rubber, ceramic-bonded grinding wheels, Electrolyte in the reduction of alumina to aluminum, ceramics, insecticide, binder for abrasives, electric insulation, explosives & polishes., For more Uses (Complete) data for ALUMINUM SODIUM FLUORIDE (9 total), please visit the HSDB record page., Use Classification: INSECTICIDES, Industry Uses: Catalyst, Not Known or Reasonably Ascertainable, Filler, Flux agent, Abrasives, Consumer Uses: Abrasives, Methods of Manufacturing: Reaction of hydrofluoric acid, hydrated alumina, and sodium carbonate., It is commonly produced by mixing sodium aluminate soln with liquid or gaseous hydrogen fluoride., ... Synthetically from aluminum fluoride, ammonium fluoride and salt., Synthetic cryolite is usually made from sodium aluminate, sodium bicarbonate, and sodium fluoride., Cryolite may be obtained by (a) mining natural mineral cryolite or (b) synthesis by the reaction of aluminum oxide, sodium chloride and hydrogen fluoride., Formulations, Preparations: Kryocide, insecticide produced by Pennwalt, 96% sodium fluoaluminate, Aqueous suspension, bait, dust and wettable powder., ... Generally and 0.2% suspension, as insecticide, Consumption Patterns: About 75% in the production and refining of aluminum, 25% in all other applications (1965), Seven thousand metric tons were applied in the United States in 1944., U.S. Production: 2023: 10, 000, 000 - <50, 000 lb, 2022: 10, 000 - <25, 2021: 10, 2020: 8, 500, 000 - <10, (1972) AT LEAST 8.8X10+10 G, U.S. Imports: (1972) 2.33X10+10 G, (1973) 3.48X10+10 G, General Manufacturing Information: All Other Basic Inorganic Chemical Manufacturing, Primary Metal Manufacturing, Other (requires additional information), Machinery Manufacturing, Miscellaneous Manufacturing, Aluminum sodium fluoride: INACTIVE, Cryolite (Na3(AlF6)): ACTIVE, Cryolite is, incompatible with alkaline pesticides such as lime sulfur, bordeaux mixture., With lime, cryolite undergoes ..., a chemical, reaction, that, ... Results in plant injury., Cryolite ... is the primary constituent of the Hall-Heroult cell electrolyte., ... Developed as a safer stomach poison insecticide than the arsenicals, especially because of concern about persistent lead arsenate residues on edible produce such as apples., ... Widely exploited since the early days of commercial aluminum production, but now practically exhausted and abandoned in favor of synthetic cryolite..

Which category does Cryolite belong to?

Category: Organic Chemicals.

PubChem Public Data

Public-database records for Cryolite (CAS 15096-52-3), reproduced here for independent cross-checking.

Safety classification and hazard statements

Reported hazard statementsH332, H372, H411, H412

H332: Harmful if inhaled [Warning Acute toxicity, inhalation]

H372: Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]

Physical description and handling notes

  • Large Crystals; CBI; Dry Powder; Other Solid
  • Colorless to white (but may also be other colors) solid; [CHEMINFO]
  • CRYSTALS OR AMORPHOUS POWDER.
  • Colorless to dark odorless solid. [pesticide] [Note: Loses color on heating.]
  • MONOCLINIC CRYSTALS (NATURAL PRODUCT); AMORPHOUS POWDER (SYNTHETIC PRODUCT)
  • Snow-white, semi-opaque masses, vitreous fracture. Monoclinic crystals with cubic habit, perfect cleavage. The natural form may be colored reddish or brown or even black, but loses this discoloration on heating.

Reported physical properties

熔点1832 °F (NIOSH, 2024)
熔点960-1027 °C
熔点1009 °C
熔点1832 °F
溶解度0.04 % (NIOSH, 2024)
溶解度0.04%
密度2.95 g/cu cm
密度2.95 g/cm³
密度2.90
蒸气压0 mmHg (approx) (NIOSH, 2024)

How this substance is indexed

CAS Registry Number15096-52-3
PubChem CID16693908
分子式AlF6.3Na
IUPAC 名称trisodium;hexafluoroaluminum(3-)
UNII(FDA)5ZIS914RQ9

Documented uses

  • Used as an electrolyte in the production of aluminum by electrolytic reduction; [ACGIH]
  • Aluminum Producing [Category: Industry]
  • Primarily a stomach poison. ... For use against Lepidoptera & Coleoptera on certain vegetables & fruit crops ... .
  • Principally an electrolyte in production and refining of aluminum; flux in production of various metals and alloys; flux and opacifier in manufacture of glass and enamels; coating for welding rods; filler for resin, rubber, ceramic-bonded grinding wheels
  • Electrolyte in the reduction of alumina to aluminum; ceramics; insecticide; binder for abrasives; electric insulation; explosives & polishes.
  • For more Uses (Complete) data for ALUMINUM SODIUM FLUORIDE (9 total), please visit the HSDB record page.

Names this substance appears under

CRYOLITE; 15096-52-3; Cryolite (Na3(AlF6)); Cryocide; Kryocide; Kryolith; ICE Spar; Cryolite (AlNa3F6); Sodium aluminum fluoride; PROKIL CRYOLITE-96; 5ZIS914RQ9; Cryodust; Icetone; Kriolit; Greenland spar; RefChem:919221

Computed molecular descriptors

分子量209.941265
氢键供体数0
氢键受体数7
可旋转键数0
精确质量209.9412652
单同位素质量209.9412652
拓扑极性表面积0
重原子数10
形式电荷0
复杂度62.7

Database abstract

Cryolite · CAS 15096-52-3 · AlF6.3Na. UNII 5ZIS914RQ9. 熔点: 1832 °F (NIOSH, 2024); 熔点: 960-1027 °C; 熔点: 1009 °C.

Source: PubChem / Wikidata; the batch COA governs where values differ.

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