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Tetramethylene sulfone

CAS 126-33-0C4H8O2SMW 120.17

Tetramethylene sulfone (CAS 126-33-0) — formula C4H8O2S, molecular weight 120.17; category organic chemicals.

Specifications

CAS Number126-33-0
Molecular FormulaC4H8O2S
Molecular Weight120.17
Melting Point79 °F (USCG, 1999)
Boiling Point545 °F at 760 mmHg (USCG, 1999)
LogP-0.8
ApplicationsUses: Used as a solvent (aromatics extraction and polymerization), plasticizer, curing agent (epoxy resins) and therapeutic (antibacterial, convulsant, and radiation-protective agent), Also used for acid gas purification, fractionation (wood tars, tall oil, and other fatty acids), and textile finishing, [HSDB] Used in electronic applications, pharmaceutical manufacturing (solvent), jet printing inks (solvent), and medicines (believed to exist only in patent literature), [SIDS UNEP], Semiconductor Manufacturing [Category: Industry], Textiles (Printing, Dyeing, or Finishing) [Category: Industry], Selective solvent for liquid-vapor extractions., Solvent for aromatics extraction, for acid gas purification., Extraction of aromatic hydrocarbons from oil refinery streams, polymerization solvent, plasticizer., Fractionation of wood tars, and other fatty acids, component of hydraulic fluid, textile finishing., For more Uses (Complete) data for SULFOLANE (6 total), please visit the HSDB record page., Industry Uses: Other, Solvent, Processing aids, specific to petroleum production, Intermediate, Cleaning agent, Consumer Uses: Solvent, Methods of Manufacturing: Prepared by catalytic hydrogenation of sulfolene oxides: Mahan, Fauske, US 2578565 (1951 to Phillips Petroleum)., ... From butadiene and sulfur dioxide ... Evans, Morris, US 2360859 (1944 to Shell)., Sulfolane ... is made by reacting sulfur dioxide and butadiene to form sulfolene, which is then hydrogenated to give sulfolane, Formulations, Preparations: Commercially available as anhydrous sulfolane and as sulfolane containing 3% wt deionized water, Grade: Technical, Sulfolane-W (97% 1, 1-tetrahydrothiophenedioxide and 3% water), U.S. Production: 2023: 1, 000, 000 - <5, 000 lb, 2022: 10, 000 - <50, 2021: 10, 2020: 10, Thiophene, tetrahydro-, 1, 1-dioxide is listed as a High Production Volume (HPV) chemical (65FR81686). Chemicals listed as HPV were produced in or imported into the U.S. in >1 million pounds in 1990 and, or 1994. The HPV list is based on the 1990 Inventory Update Rule. (IUR) (40 CFR part 710 subpart B, 51FR21438)., (1986) >1 million - 10 million pounds, (1990) >1 million - 10 million pounds, (1994) >1 million - 10 million pounds, For more U.S. Production (Complete) data for SULFOLANE (7 total), U.S. Imports: (1972) NEGLIGIBLE, U.S. Exports: (1972) NEGLIGIBLE, General Manufacturing Information: Petrochemical Manufacturing, All Other Basic Organic Chemical Manufacturing, All other Petroleum and Coal Products Manufacturing, Petroleum Refineries, Adhesive Manufacturing, Computer and Electronic Product Manufacturing, Pharmaceutical and Medicine Manufacturing, All Other Basic Inorganic Chemical Manufacturing, 1-dioxide: ACTIVE
CategoryOrganic Chemicals

Where it is used

Documented applications: Uses: Used as a solvent (aromatics extraction and polymerization), plasticizer, curing agent (epoxy resins) and therapeutic (antibacterial, convulsant, and radiation-protective agent), Also used for acid gas purification, fractionation (wood tars, tall oil, and other fatty acids), and textile finishing, [HSDB] Used in electronic applications, pharmaceutical manufacturing (solvent), jet printing inks (solvent), and medicines (believed to exist only in patent literature), [SIDS UNEP], Semiconductor Manufacturing [Category: Industry], Textiles (Printing, Dyeing, or Finishing) [Category: Industry], Selective solvent for liquid-vapor extractions., Solvent for aromatics extraction, for acid gas purification., Extraction of aromatic hydrocarbons from oil refinery streams, polymerization solvent, plasticizer., Fractionation of wood tars, and other fatty acids, component of hydraulic fluid, textile finishing., For more Uses (Complete) data for SULFOLANE (6 total), please visit the HSDB record page., Industry Uses: Other, Solvent, Processing aids, specific to petroleum production, Intermediate, Cleaning agent, Consumer Uses: Solvent, Methods of Manufacturing: Prepared by catalytic hydrogenation of sulfolene oxides: Mahan, Fauske, US 2578565 (1951 to Phillips Petroleum)., ... From butadiene and sulfur dioxide ... Evans, Morris, US 2360859 (1944 to Shell)., Sulfolane ... is made by reacting sulfur dioxide and butadiene to form sulfolene, which is then hydrogenated to give sulfolane, Formulations, Preparations: Commercially available as anhydrous sulfolane and as sulfolane containing 3% wt deionized water, Grade: Technical, Sulfolane-W (97% 1, 1-tetrahydrothiophenedioxide and 3% water), U.S. Production: 2023: 1, 000, 000 - <5, 000 lb, 2022: 10, 000 - <50, 2021: 10, 2020: 10, Thiophene, tetrahydro-, 1, 1-dioxide is listed as a High Production Volume (HPV) chemical (65FR81686). Chemicals listed as HPV were produced in or imported into the U.S. in >1 million pounds in 1990 and, or 1994. The HPV list is based on the 1990 Inventory Update Rule. (IUR) (40 CFR part 710 subpart B, 51FR21438)., (1986) >1 million - 10 million pounds, (1990) >1 million - 10 million pounds, (1994) >1 million - 10 million pounds, For more U.S. Production (Complete) data for SULFOLANE (7 total), U.S. Imports: (1972) NEGLIGIBLE, U.S. Exports: (1972) NEGLIGIBLE, General Manufacturing Information: Petrochemical Manufacturing, All Other Basic Organic Chemical Manufacturing, All other Petroleum and Coal Products Manufacturing, Petroleum Refineries, Adhesive Manufacturing, Computer and Electronic Product Manufacturing, Pharmaceutical and Medicine Manufacturing, All Other Basic Inorganic Chemical Manufacturing, 1-dioxide: ACTIVE.

Purchase Profile

What this product is

Tetramethylene sulfone is a carbon-based organic compound with CAS registry number 126-33-0 and molecular formula C4H8O2S (molecular weight 120.17), belonging to the organic chemicals segment of chemical raw materials.

Identification

CAS number: 126-33-0

Its molecular formula C4H8O2S comprises 4 C, 8 H, 2 O, 1 S atoms.

Also known as: Tetramethylene sulfone · Sulfolane

Category: organic chemicals

Frequently Asked Questions

What is the CAS number of Tetramethylene sulfone?

The CAS registry number of Tetramethylene sulfone is 126-33-0.

What is the molecular formula and molecular weight of Tetramethylene sulfone?

Molecular formula C4H8O2S, molecular weight 120.17.

What other names is Tetramethylene sulfone known by?

It is also registered under: Tetramethylene sulfone, Sulfolane.

What are the documented applications of Tetramethylene sulfone?

Recorded applications: Uses: Used as a solvent (aromatics extraction and polymerization), plasticizer, curing agent (epoxy resins) and therapeutic (antibacterial, convulsant, and radiation-protective agent), Also used for acid gas purification, fractionation (wood tars, tall oil, and other fatty acids), and textile finishing, [HSDB] Used in electronic applications, pharmaceutical manufacturing (solvent), jet printing inks (solvent), and medicines (believed to exist only in patent literature), [SIDS UNEP], Semiconductor Manufacturing [Category: Industry], Textiles (Printing, Dyeing, or Finishing) [Category: Industry], Selective solvent for liquid-vapor extractions., Solvent for aromatics extraction, for acid gas purification., Extraction of aromatic hydrocarbons from oil refinery streams, polymerization solvent, plasticizer., Fractionation of wood tars, and other fatty acids, component of hydraulic fluid, textile finishing., For more Uses (Complete) data for SULFOLANE (6 total), please visit the HSDB record page., Industry Uses: Other, Solvent, Processing aids, specific to petroleum production, Intermediate, Cleaning agent, Consumer Uses: Solvent, Methods of Manufacturing: Prepared by catalytic hydrogenation of sulfolene oxides: Mahan, Fauske, US 2578565 (1951 to Phillips Petroleum)., ... From butadiene and sulfur dioxide ... Evans, Morris, US 2360859 (1944 to Shell)., Sulfolane ... is made by reacting sulfur dioxide and butadiene to form sulfolene, which is then hydrogenated to give sulfolane, Formulations, Preparations: Commercially available as anhydrous sulfolane and as sulfolane containing 3% wt deionized water, Grade: Technical, Sulfolane-W (97% 1, 1-tetrahydrothiophenedioxide and 3% water), U.S. Production: 2023: 1, 000, 000 - <5, 000 lb, 2022: 10, 000 - <50, 2021: 10, 2020: 10, Thiophene, tetrahydro-, 1, 1-dioxide is listed as a High Production Volume (HPV) chemical (65FR81686). Chemicals listed as HPV were produced in or imported into the U.S. in >1 million pounds in 1990 and, or 1994. The HPV list is based on the 1990 Inventory Update Rule. (IUR) (40 CFR part 710 subpart B, 51FR21438)., (1986) >1 million - 10 million pounds, (1990) >1 million - 10 million pounds, (1994) >1 million - 10 million pounds, For more U.S. Production (Complete) data for SULFOLANE (7 total), U.S. Imports: (1972) NEGLIGIBLE, U.S. Exports: (1972) NEGLIGIBLE, General Manufacturing Information: Petrochemical Manufacturing, All Other Basic Organic Chemical Manufacturing, All other Petroleum and Coal Products Manufacturing, Petroleum Refineries, Adhesive Manufacturing, Computer and Electronic Product Manufacturing, Pharmaceutical and Medicine Manufacturing, All Other Basic Inorganic Chemical Manufacturing, 1-dioxide: ACTIVE.

Which category does Tetramethylene sulfone belong to?

Category: Organic Chemicals.

PubChem Public Data

Public-database records for Tetramethylene sulfone (CAS 126-33-0), reproduced here for independent cross-checking.

Safety classification and hazard statements

Reported hazard statementsH302, H360 (22.7%), H320, H361

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P264, P270, P301+P317, P330, and P501 (click each P-code to see the statement)

Physical description and handling notes

  • Sulfolane is a colorless oily liquid with a weak oily odor. Solidifies (freezing point is 79 °F) and sinks on first contact with water, then mixes with water. (USCG, 1999)
  • Liquid; Other Solid
  • Liquid; mp = 27.4-27.8 deg C; [Merck Index] White solid; [HSDB] Colorless liquid; mp = 26 deg C; [CAMEO] Colorless solid; mp = 27 deg C; [SIDS UNEP] Colorless crystalline solid; mp = 25-28 deg C; [Alfa Aesar MSDS]
  • White or creamy white, crystalline powder
  • Odorless
  • Slightly bitter taste

Reported physical properties

沸点545 °F at 760 mmHg (USCG, 1999)
沸点285 °C
沸点285 °C @760 [mm Hg]
熔点79 °F (USCG, 1999)
熔点27.4-27.8 °C
闪点330 °F (USCG, 1999)
闪点177 °C (350 °F) (OPEN CUP)
密度1.2606 at 30 °C/4 °C
密度1.261 @25 °C
蒸气压0.0062 [mmHg]

How this substance is indexed

CAS Registry Number126-33-0
PubChem CID31347
分子式C4H8O2S
IUPAC 名称thiolane 1,1-dioxide
UNII(FDA)Y5L06AH4G5

Documented uses

  • Used as a solvent (aromatics extraction and polymerization), plasticizer, curing agent (epoxy resins) and therapeutic (antibacterial, convulsant, and radiation-protective agent); Also used for acid gas purification, fractionation (wood tars, tall oil, and other fatty acids), and textile finishing; [HSDB] Used in electronic applications, pharmaceutical manufacturing (solvent), jet printing inks (solvent), and medicines (believed to exist only in patent literature); [SIDS UNEP]
  • Semiconductor Manufacturing [Category: Industry]
  • Textiles (Printing, Dyeing, or Finishing) [Category: Industry]
  • Selective solvent for liquid-vapor extractions.
  • Solvent for aromatics extraction; for acid gas purification.
  • Extraction of aromatic hydrocarbons from oil refinery streams; polymerization solvent; plasticizer.

Names this substance appears under

SULFOLANE; 126-33-0; Tetrahydrothiophene 1,1-dioxide; Tetramethylene sulfone; Sulfolan; 1,1-Dioxothiolan; Sulpholane; Thiophene, tetrahydro-, 1,1-dioxide; thiolane 1,1-dioxide; Sulfalone; Sulphoxaline; Dioxothiolan; Thiophan sulfone; Bondelane A; Bondolane A; Thiophane dioxide

Computed molecular descriptors

分子量120.17
XLogP3-0.8
氢键供体数0
氢键受体数2
可旋转键数0
精确质量120.02450067
单同位素质量120.02450067
拓扑极性表面积42.5
重原子数7
形式电荷0

Database abstract

Tetramethylene sulfone · CAS 126-33-0 · C4H8O2S. UNII Y5L06AH4G5. 沸点: 545 °F at 760 mmHg (USCG, 1999); 沸点: 285 °C; 沸点: 285 °C @760 [mm Hg].

Source: PubChem / Wikidata; the batch COA governs where values differ.

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