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Home › Product Catalog › 2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane

2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane

CAS 108-62-3C8H16O4MW 176.21

2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane (CAS 108-62-3) — formula C8H16O4, molecular weight 176.21; category organic chemicals.

Specifications

CAS Number108-62-3
Molecular FormulaC8H16O4
Molecular Weight176.21
Melting Point246.2 °C (closed capillary)
Boiling Point115 °C (sublimes)
LogPlog Kow = 0.12
ApplicationsUses: Used for control of snails in seed crops, turf, ornamentals, berries, citrus, vegetables, and other crops, [Reference #1] Used for synthesis in the chemical industry, as odor agent, and as pesticide, [IUCLID] Used as molluscicide, solid fuel for small heaters (alcohol replacement), and fire starter, [Reference #2], Farming (Pesticides) [Category: Industry], For metaldehyde (USEPA, OPP Pesticide Code: 053001) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., Metaldehyde is a molluscicide used to control snails and slugs on a wide variety of sites, including turf, and vegetables., In compressed form as a fuel instead of alcohol, molluscicide., Polymer, Metaldehyde is used as a pesticide against slugs, snails, and other gastropods, it is also used in tablets as a solid fuel for small heaters, and as fire-starter. (L1782), Use Classification: Molluscicides, Environmental transformation -> Pesticides (parent, predecessor), Household Products: Information on 12 consumer products that contain Metaldehyde [BSI:ISO] in the following categories is provided:, • Pesticides, Information on 4 consumer products that contain Metaldehyde in the following categories is provided:, Methods of Manufacturing: Metaldehyde is obtained in addition to large amounts of paraldehyde during polymerization of acetaldehyde in the presence of HBr and alkaline earth metal bromides, such as CaBr2, at temperatures below 0 °C. However, yields are scarcely higher than 8%. Yields of 14 - 20% have been reported when working in the presence of 7 - 15% of an aliphatic or cyclic ether at 0 - 20 °C. Insoluble metaldehyde is filtered out. Acetaldehyde is then distilled from the filtrate following depolymerization of the paraldehyde and is returned to the polymerization. Recycling of the large amounts of acetaldehyde results in losses that increase the process costs., Prepd by polymerization of acetaldehyde in presence of hydrochloric acid, sulfuric acid @ low temp: Kekule, Zincke, Ann 162, 125 (1872), in presence of pyridine and hydrogen bromide: Wilder, US patent 2, 426, 961 (1947 to Publicker Ind)., Formulations, Preparations: Corry's Slug, Snail & Insect Killer, Get-A-Bug Snail, Slug & Insect Killer : Active ingredients 2.0%Metaldehyde, 5.0% Carbaryl, Bug-Geta Snail & Slug Pellets: Active ingredient 3.25% Metaldehyde, Durham Metaldehyde Granules 3.5: Active ingredient 3.5% Metaldehyde, Corry's Liquid Slug & Snail Control, Deadline Bullets, Deadline M-PS Mini-Pellets!, Metaldehyde 4 Bait, Metarex 4% Snail And Slug Bait: Active ingredient 4.0% Metaldehyde, For more Formulations, Preparations (Complete) data for Metaldehyde (29 total), please visit the HSDB record page., U.S. Production: Production volumes for non-confidential chemicals reported under the Inventory Update Rule. [Table#3513], General Manufacturing Information: The WHO Recommended Classification of Pesticides by Hazard identifies Metaldehyde (technical grade) as Class II: moderately hazardous, Main Use: molluscicide.
CategoryOrganic Chemicals

Where it is used

Documented applications: Uses: Used for control of snails in seed crops, turf, ornamentals, berries, citrus, vegetables, and other crops, [Reference #1] Used for synthesis in the chemical industry, as odor agent, and as pesticide, [IUCLID] Used as molluscicide, solid fuel for small heaters (alcohol replacement), and fire starter, [Reference #2], Farming (Pesticides) [Category: Industry], For metaldehyde (USEPA, OPP Pesticide Code: 053001) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., Metaldehyde is a molluscicide used to control snails and slugs on a wide variety of sites, including turf, and vegetables., In compressed form as a fuel instead of alcohol, molluscicide., Polymer, Metaldehyde is used as a pesticide against slugs, snails, and other gastropods, it is also used in tablets as a solid fuel for small heaters, and as fire-starter. (L1782), Use Classification: Molluscicides, Environmental transformation -> Pesticides (parent, predecessor), Household Products: Information on 12 consumer products that contain Metaldehyde [BSI:ISO] in the following categories is provided:, • Pesticides, Information on 4 consumer products that contain Metaldehyde in the following categories is provided:, Methods of Manufacturing: Metaldehyde is obtained in addition to large amounts of paraldehyde during polymerization of acetaldehyde in the presence of HBr and alkaline earth metal bromides, such as CaBr2, at temperatures below 0 °C. However, yields are scarcely higher than 8%. Yields of 14 - 20% have been reported when working in the presence of 7 - 15% of an aliphatic or cyclic ether at 0 - 20 °C. Insoluble metaldehyde is filtered out. Acetaldehyde is then distilled from the filtrate following depolymerization of the paraldehyde and is returned to the polymerization. Recycling of the large amounts of acetaldehyde results in losses that increase the process costs., Prepd by polymerization of acetaldehyde in presence of hydrochloric acid, sulfuric acid @ low temp: Kekule, Zincke, Ann 162, 125 (1872), in presence of pyridine and hydrogen bromide: Wilder, US patent 2, 426, 961 (1947 to Publicker Ind)., Formulations, Preparations: Corry's Slug, Snail & Insect Killer, Get-A-Bug Snail, Slug & Insect Killer : Active ingredients 2.0%Metaldehyde, 5.0% Carbaryl, Bug-Geta Snail & Slug Pellets: Active ingredient 3.25% Metaldehyde, Durham Metaldehyde Granules 3.5: Active ingredient 3.5% Metaldehyde, Corry's Liquid Slug & Snail Control, Deadline Bullets, Deadline M-PS Mini-Pellets!, Metaldehyde 4 Bait, Metarex 4% Snail And Slug Bait: Active ingredient 4.0% Metaldehyde, For more Formulations, Preparations (Complete) data for Metaldehyde (29 total), please visit the HSDB record page., U.S. Production: Production volumes for non-confidential chemicals reported under the Inventory Update Rule. [Table#3513], General Manufacturing Information: The WHO Recommended Classification of Pesticides by Hazard identifies Metaldehyde (technical grade) as Class II: moderately hazardous, Main Use: molluscicide..

Purchase Profile

What this product is

2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane is a carbon-based organic compound with CAS registry number 108-62-3 and molecular formula C8H16O4 (molecular weight 176.21), belonging to the organic chemicals segment of chemical raw materials.

Identification

CAS number: 108-62-3

Its molecular formula C8H16O4 comprises 8 C, 16 H, 4 O atoms.

Also known as: 2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane · Metaldehyde

Category: organic chemicals

Frequently Asked Questions

What is the CAS number of 2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane?

The CAS registry number of 2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane is 108-62-3.

What is the molecular formula and molecular weight of 2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane?

Molecular formula C8H16O4, molecular weight 176.21.

What other names is 2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane known by?

It is also registered under: 2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane, Metaldehyde.

What are the documented applications of 2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane?

Recorded applications: Uses: Used for control of snails in seed crops, turf, ornamentals, berries, citrus, vegetables, and other crops, [Reference #1] Used for synthesis in the chemical industry, as odor agent, and as pesticide, [IUCLID] Used as molluscicide, solid fuel for small heaters (alcohol replacement), and fire starter, [Reference #2], Farming (Pesticides) [Category: Industry], For metaldehyde (USEPA, OPP Pesticide Code: 053001) ACTIVE products with label matches., SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses., Metaldehyde is a molluscicide used to control snails and slugs on a wide variety of sites, including turf, and vegetables., In compressed form as a fuel instead of alcohol, molluscicide., Polymer, Metaldehyde is used as a pesticide against slugs, snails, and other gastropods, it is also used in tablets as a solid fuel for small heaters, and as fire-starter. (L1782), Use Classification: Molluscicides, Environmental transformation -> Pesticides (parent, predecessor), Household Products: Information on 12 consumer products that contain Metaldehyde [BSI:ISO] in the following categories is provided:, • Pesticides, Information on 4 consumer products that contain Metaldehyde in the following categories is provided:, Methods of Manufacturing: Metaldehyde is obtained in addition to large amounts of paraldehyde during polymerization of acetaldehyde in the presence of HBr and alkaline earth metal bromides, such as CaBr2, at temperatures below 0 °C. However, yields are scarcely higher than 8%. Yields of 14 - 20% have been reported when working in the presence of 7 - 15% of an aliphatic or cyclic ether at 0 - 20 °C. Insoluble metaldehyde is filtered out. Acetaldehyde is then distilled from the filtrate following depolymerization of the paraldehyde and is returned to the polymerization. Recycling of the large amounts of acetaldehyde results in losses that increase the process costs., Prepd by polymerization of acetaldehyde in presence of hydrochloric acid, sulfuric acid @ low temp: Kekule, Zincke, Ann 162, 125 (1872), in presence of pyridine and hydrogen bromide: Wilder, US patent 2, 426, 961 (1947 to Publicker Ind)., Formulations, Preparations: Corry's Slug, Snail & Insect Killer, Get-A-Bug Snail, Slug & Insect Killer : Active ingredients 2.0%Metaldehyde, 5.0% Carbaryl, Bug-Geta Snail & Slug Pellets: Active ingredient 3.25% Metaldehyde, Durham Metaldehyde Granules 3.5: Active ingredient 3.5% Metaldehyde, Corry's Liquid Slug & Snail Control, Deadline Bullets, Deadline M-PS Mini-Pellets!, Metaldehyde 4 Bait, Metarex 4% Snail And Slug Bait: Active ingredient 4.0% Metaldehyde, For more Formulations, Preparations (Complete) data for Metaldehyde (29 total), please visit the HSDB record page., U.S. Production: Production volumes for non-confidential chemicals reported under the Inventory Update Rule. [Table#3513], General Manufacturing Information: The WHO Recommended Classification of Pesticides by Hazard identifies Metaldehyde (technical grade) as Class II: moderately hazardous, Main Use: molluscicide..

Which category does 2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane belong to?

Category: Organic Chemicals.

PubChem Public Data

Public-database records for 2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane (CAS 108-62-3), reproduced here for independent cross-checking.

Safety classification and hazard statements

Reported hazard statementsH228, H301, H412, H312 (17.2%), H361 (11.9%), H320, H370, H373

H228: Flammable solid [Danger Flammable solids]

H301: Toxic if swallowed [Danger Acute toxicity, oral]

Physical description and handling notes

  • Metaldehyde is a white-colored crystalline solid. It is insoluble in water. It is highly flammable and when ignited will give off irritating fumes. It may be toxic by ingestion and is very irritating to skin and eyes. It is used to make other chemicals.
  • Solid; [IUCLID] Formulated as granules, pellets, mini-pellets, meal, paste, and liquid; [Reference #1] Colorless or white solid; [Reference #2] White odorless powder; [Alfa Aesar MSDS]
  • Crystalline powder
  • Crystals
  • Menthol odor
  • In water, 200 mg/L at 17 °C /Polymer/

Reported physical properties

沸点115 °C (sublimes)
熔点246.2 °C (closed capillary)
闪点97 °F (36 °C) (closed cup)
溶解度In water, 222 mg/L at 20 °C
密度1.27 at 20 °C
蒸气压6.6X10+3 mPa (5.0X10-2 mm Hg) at 25 °C
LogPlog Kow = 0.12
Heat of Combustion3370 kJ/mol

How this substance is indexed

CAS Registry Number108-62-3
PubChem CID61021
分子式C8H16O4
IUPAC 名称2,4,6,8-tetramethyl-1,3,5,7-tetraoxocane
UNII(FDA)4CI033VJYG

Documented uses

  • Metaldehyde is a molluscicide used to control snails and slugs on a wide variety of sites, including turf, ornamentals, berries, citrus, and vegetables.
  • In compressed form as a fuel instead of alcohol; molluscicide. /Polymer/
  • Information on 12 consumer products that contain Metaldehyde [BSI:ISO] in the following categories is provided:
  • Information on 4 consumer products that contain Metaldehyde in the following categories is provided:
  • Prepd by polymerization of acetaldehyde in presence of hydrochloric acid, sulfuric acid @ low temp: Kekule, Zincke, Ann 162, 125 (1872); in presence of pyridine and hydrogen bromide: Wilder, US patent 2,426,961 (1947 to Publicker Ind).
  • Production volumes for non-confidential chemicals reported under the Inventory Update Rule. [Table#3513]

Names this substance appears under

METALDEHYDE; 108-62-3; Metacetaldehyde; Slug-Tox; 2,4,6,8-Tetramethyl-1,3,5,7-tetraoxocane; Cekumeta; Acetaldehyde, tetramer; Ariotox; Halizan; Metason; 1,3,5,7-Tetroxocane, 2,4,6,8-tetramethyl-; Metaldehyd; Corry's Slug Death; Metaldeide; Acetaldehyde Tetramer; 2,4,6,8-Tetramethyl-1,3,5,7-tetraoxacyclooctane

Computed molecular descriptors

分子量176.21
XLogP31.1
氢键供体数0
氢键受体数4
可旋转键数0
精确质量176.10485899
单同位素质量176.10485899
拓扑极性表面积36.9
重原子数12
形式电荷0

Database abstract

2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane · CAS 108-62-3 · C8H16O4. UNII 4CI033VJYG. 沸点: 115 °C (sublimes); 熔点: 246.2 °C (closed capillary); 闪点: 97 °F (36 °C) (closed cup).

Source: PubChem / Wikidata; the batch COA governs where values differ.

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